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- Management
- Research subdivisions
- The Press Studies Research institute
- The Ukrainian Periodicals Research Department
- The Foreign Languages Periodicals Research Department
- The Bibliographical Research Department
- The Ukrainian Press National Bibliography Department
- The Modern Informational and Library Technologies Institute
- The “Cataloging and Catalogue Systems Organization” Division
- The Research Group
- The Authoritative Records Database Formation Section
- The Acquisitions Cataloging and Electronic Catalogue Organization Department
- The Documents Cataloging Section
- The Readers’ Requests Reception and Catalogues Related Readers Servicing Section
- The Re-Cataloging and Card Catalogues Department
- The Documents Re-Cataloging Section
- The Card Catalogues Support and Retro-Conversion Section
- The “Quick” Cataloging Section
- The Automated Information Processing and Innovational Library Techniques Department
- The Organizational and Methodological Assistance for Innovational Library Techniques Group
- The Electronic Catalogue and Database Support Section
- The Readers Servicing with Electronic Resources Section
- The Information Techniques Section
- The Information Resources Formation Department
- The Periodicals Section
- The Ukrainian Books Section
- The Foreign Languages Books and Book Exchange Section
- "Tetyana and Omelyan Antonovych palace of arts" division
- Fine and music art works research department
- Department of scientific and inforrmational, organisation and exhibitory work
- The Information & Referral and Exhibition Work Department
- The Research Work Information Support Group
- Exhibition and Excursion Activities Section
- The Readers Registration and Information & Referral Work Group
- The Copying Service Group
- Scientific bibliography department
- Scientific group
- Sector of readers servicing and organisation of bibliographic information staff
- Rare books department
- Sector of organisation and scientific processing of ancient printings funds
- Sector of rare publications Õ²Õ-ÕÕ ñentury
- Historic collections research department
- Library science department
- Manuscripts department
- Scientific group
- Sector of scientific forming of anuscript funds and readers servicing
- Ukrainica department
- Department of scientific restoration and preservation of rare publications
- Research laboratory
- Sector of restoration and preservation of books
- Hygienics group
- Marian and Ivanna Kots periodacals scientific department
- Sector of periodicals reading hall
- Sector of scientific processing of periodicals
- Sector of reader claims fulfilment and periodicals fund organisation
- Sector of rare periodicals of Õ²Õ-ÕÕ century
- Scientific edition and publishing department
- Group of software elaboration of scientific themes of library
- Cartography office
- Research, organisation and technical departments
- Readers servicing department
- Sector of reading halls
- Reader registration group
- German literature office
- German reading hall
- Austrian reading hall
- Exchange and reserve funds and retrospective acquisition department
- Exchange funds organisation group
- Group of reserve funds organisation and retrospective acquisition
- Main books fund department
- Sector of fulfilment of readers claims from main book depository
- Sector of fulfilment of readers claims from book depository "Citadel"
- Sector of new literature reception and distribution and selection of literature for amortisation
- Sector of depositary literature storage
- Reader claims control group
- Polygraphy and primary funds restoration department
- Administrative and supply section
- Guards staff
